It's the eponymous self-described aloof curmudgeonly late-1990s MTV star, Daria. Trained from a number of screencaps from the last couple seasons of the show.
helper tags: brown hair, long hair, round-rimmed eyewear, lips, dot eyes
probably want to make liberal use of the bored eyes and expressionless tags
outfit: (short green) jacket, (orange) shirt, (black) skirt, (black) combat boots